Static IP doesn't work

Volumio2 seems to ignore a static IP setup. As in the attached screen shot.

Strangely, with this setup, I can access the Volumio web interface on both addresses, and

However when I reboot the RPi, it goes back to dynamic only and the servies is no longer available on

Screen Shot 2016-07-16 at 8.29.29 PM.jpg

Already reported