You have something strange going on – The daemon starts up fine initially,
Mar 23 20:35:17 volumiokefe volumio[1295]: vollibrespot v0.2.2 cd96399 2020-10-07 (librespot 08d8bcc 2020-10-07) -- Built On 2020-10-07
Mar 23 20:35:17 volumiokefe volumio[1295]: Reading Config from "volspotify.toml"
Mar 23 20:35:17 volumiokefe volumio[1295]: [Vollibrespot] : Using Alsa backend with device: softvolume
But then later seems to have a corrupted config file:
Mar 23 20:36:16 volumiokefe volumio[1715]: Malformed config key: expected an equals, found a newline at line 33 column 4
Mar 23 20:36:16 volumiokefe systemd[1]: volspotconnect2.service: main process exited, code=exited, status=1/FAILURE
Could you reboot your system and send a fresh log? You can just paste the generated log link instead of a text file 