I had a similar problem with Raspyfi and gave up. With Volumio I hope I may be able to solve the problem because it gives some error messages unlike Raspyfi.
Symptoms - I’m connected and set-up OK working over WiFi. I can play Webradio fine, but cannot get the NAS to mount.
The first few times I think I just had the path wrong with too many slashes etc so it could not find a mount of that name. Now I think I have the correct path because is now says “mount: Operation not supported”. I’m using Windows 7 laptop and trying to mount my NAS which has a fixed IP on the LAN. The NAS is definitely aliove on the network - I can ping it and can navigate to it and open files (via windows 7 PC)
I’m using SMB/CIFS, but have also tried NFS with no success.
Can anyone advise? Please go gently as I am a complete novice with Ubuntu, although I’m very familiar with the concept of MS-DOS command prompt window. I have Putty installed and can run commands by cutting and pasting, but have zero understanding of what the commands actually mean!